The Geiger-Marsden experiment, also called the gold foil experiment or the α-particle scattering experiments, refers to a series of early-20th-century experiments that gave physicists their first view of the structure of the atomic nucleus and the physics underlying the everyday world. It was first proposed by Nobel Prize-winning physicist Ernest Rutherford.
As familiar as terms like electron, proton and neutron are to us now, in the early 1900s, scientists had very little concept of the fundamental particles that made up atoms.
In fact, until 1897, scientists believed that atoms had no internal structure and believed that they were an indivisible unit of matter. Even the label "atom" gives this impression, given that it's derived from the Greek word "atomos," meaning "indivisible."
J.J. Thomson model of the atom
But that year, University of Cambridge physicist Joseph John Thomson discovered the electron and disproved the concept of the atom being unsplittable, according to Britannica. Thomson found that metals emitted negatively charged particles when illuminated with high-frequency light.
His discovery of electrons also suggested that there were more elements to atomic structure. That's because matter is usually electrically neutral; so if atoms contain negatively charged particles, they must also contain a source of equivalent positive charge to balance out the negative charge.
By 1904, Thomson had suggested a "plum pudding model" of the atom in which an atom comprises a number of negatively charged electrons in a sphere of uniform positive charge, distributed like blueberries in a muffin.
The model had serious shortcomings, however — primarily the mysterious nature of this positively charged sphere. One scientist who was skeptical of this model of atoms was Rutherford, who won the Nobel Prize in chemistry for his 1899 discovery of a form of radioactive decay via α-particles — two protons and two neutrons bound together and identical to a helium-4 nucleus, even if the researchers of the time didn't know this.
Rutherford's Nobel-winning discovery of α particles formed the basis of the gold foil experiment, which cast doubt on the plum pudding model. His experiment would probe atomic structure with high-velocity α-particles emitted by a radioactive source. He initially handed off his investigation to two of his protégés, Ernest Marsden and Hans Geiger, according to Britannica.
Rutherford reasoned that if Thomson's plum pudding model was correct, then when an α-particle hit a thin foil of gold, the particle should pass through with only the tiniest of deflections. This is because α-particles are 7,000 times more massive than the electrons that presumably made up the interior of the atom.
Gold foil experiments
Marsden and Geiger conducted the experiments primarily at the Physical Laboratories of the University of Manchester in the U.K. between 1908 and 1913.
The duo used a radioactive source of α-particles facing a thin sheet of gold or platinum surrounded by fluorescent screens that glowed when struck by the deflected particles, thus allowing the scientists to measure the angle of deflection.
The research team calculated that if Thomson's model was correct, the maximum deflection should occur when the α-particle grazed an atom it encountered and thus experienced the maximum transverse electrostatic force. Even in this case, the plum pudding model predicted a maximum deflection angle of just 0.06 degrees.
Of course, an α-particle passing through an extremely thin gold foil would still encounter about 1,000 atoms, and thus its deflections would be essentially random. Even with this random scattering, the maximum angle of refraction if Thomson's model was correct would be just over half a degree. The chance of an α-particle being reflected back was just 1 in 10^1,000 (1 followed by a thousand zeroes).
Yet, when Geiger and Marsden conducted their eponymous experiment, they found that in about 2% of cases, the α-particle underwent large deflections. Even more shocking, around 1 in 10,000 α-particles were reflected directly back from the gold foil.
Rutherford explained just how extraordinary this result was, likening it to firing a 15-inch (38 centimeters) shell (projectile) at a sheet of tissue paper and having it bounce back at you, according to Britannica
Rutherford model of the atom?
Extraordinary though they were, the results of the Geiger-Marsden experiments did not immediately cause a sensation in the physics community. Initially, the data were unnoticed or even ignored, according to the book "Quantum Physics: An Introduction" by J. Manners.
The results did have a profound effect on Rutherford, however, who in 1910 set about determining a model of atomic structure that would supersede Thomson's plum pudding model, Manners wrote in his book.
The Rutherford model of the atom, put forward in 1911, proposed a nucleus, where the majority of the particle's mass was concentrated, according to Britannica. Surrounding this tiny central core were electrons, and the distance at which they orbited determined the size of the atom. The model suggested that most of the atom was empty space.
When the α-particle approaches within 10^-13 meters of the compact nucleus of Rutherford's atomic model, it experiences a repulsive force around a million times more powerful than it would experience in the plum pudding model. This explains the large-angle scatterings seen in the Geiger-Marsden experiments.
Later Geiger-Marsden experiments were also instrumental; the 1913 tests helped determine the upper limits of the size of an atomic nucleus. These experiments revealed that the angle of scattering of the α-particle was proportional to the square of the charge of the atomic nucleus, or Z, according to the book "Quantum Physics of Matter," published in 2000 and edited by Alan Durrant.
In 1920, James Chadwick used a similar experimental setup to determine the Z value for a number of metals. The British physicist went on to discover the neutron in 1932, delineating it as a separate particle from the proton, the American Physical Society said.
What did the Rutherford model get right and wrong?
Yet the Rutherford model shared a critical problem with the earlier plum pudding model of the atom: The orbiting electrons in both models should be continuously emitting electromagnetic energy, which would cause them to lose energy and eventually spiral into the nucleus. In fact, the electrons in Rutherford's model should have lasted less than 10^-5 seconds.
Another problem presented by Rutherford's model is that it doesn't account for the sizes of atoms.
Despite these failings, the Rutherford model derived from the Geiger-Marsden experiments would become the inspiration for Niels Bohr's atomic model of hydrogen, for which he won a Nobel Prize in Physics.
Bohr united Rutherford's atomic model with the quantum theories of Max Planck to determine that electrons in an atom can only take discrete energy values, thereby explaining why they remain stable around a nucleus unless emitting or absorbing a photon, or light particle.
Thus, the work of Rutherford, Geiger (who later became famous for his invention of a radiation detector) and Marsden helped to form the foundations of both quantum mechanics and particle physics.
Rutherford's idea of firing a beam at a target was adapted to particle accelerators during the 20th century. Perhaps the ultimate example of this type of experiment is the Large Hadron Collider near Geneva, which accelerates beams of particles to near light speed and slams them together.
Additional Resources
- See a modern reconstruction of the Geiger-Marsden gold foil experiment conducted by BackstageScience and explained by particle physicist Bruce Kennedy.
- Find out more about the Bohr model of the atom which would eventually replace the Rutherford atomic model.
- Rutherford's protege Hans Gieger would eventually become famous for the invention of a radioactive detector, the Gieger counter. SciShow explains how they work.
Bibliography
Thomson's Atomic Model, Lumens Chemistry for Non-Majors,.
Rutherford Model, Britannica, https://www.britannica.com/science/Rutherford-model
Alpha particle, U.S NRC, https://www.nrc.gov/reading-rm/basic-ref/glossary/alpha-particle.html
Manners. J., et al, 'Quantum Physics: An Introduction,' Open University, 2008.
Durrant, A., et al, 'Quantum Physics of Matter,' Open University, 2008
Ernest Rutherford, Britannica, https://www.britannica.com/biography/Ernest-Rutherford
Niels Bohr, The Nobel Prize, https://www.nobelprize.org/prizes/physics/1922/bohr/facts/
House. J. E., 'Origins of Quantum Theory,' Fundamentals of Quantum Mechanics (Third Edition), 2018
